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Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy

Received: 3 February 2021     Accepted: 10 February 2021     Published: 27 February 2021
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Abstract

Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.

Published in Engineering Science (Volume 6, Issue 1)
DOI 10.11648/j.es.20210601.12
Page(s) 12-16
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Al-based Amorphous Alloy, Electrocoagulation, Oil Wastewater, COD Removal Rate, Degradation

References
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[2] Guo R L, Shi Y, Wang Z Z. Research development on organics removal in reverse osmosis concentrates [J]. Technology of Water Treahnent, 2013, 39 (4): 1-14.
[3] Ahmadi S, Sardari E, et al. Removal of oil from biodiesel wastewater by electrocoagulation method [J]. The Korean Journal of Chemical Engineering, 2013, 30 (3): 634-641.
[4] Sravanth T, Ramesh ST, Gandhimathi R, Nidheesh PV Continuous treatability of oily wastewater from locomotive wash facilities by electrocoagulation. Sep Sci Technol [J]. 2020, 55 (3): 583–589.
[5] Daghrir R, Drogui P. Electrochemical treatment of domestic wastewater using boron-doped diamond and nanostructured amorphous carbon electrodes [J]. Environmental Science and Pollution Research, 2014, 21 (10): 6578-6589.
[6] Boopathy R, Trupti D, et al. New approach of integrated advanced oxidation processes for the treatment of lube oil processing wastewater [J]. Arab J Sci Eng 2018, 43 (11): 6229–6236.
[7] Ahmadi S, Sardari E, Javadian HR, Katal R, Sefti MV. Removal of oil from biodiesel wastewater by electrocoagulation method. Korean J Chem Eng, 2013, 30 (3): 634–641.
[8] Ma X, Zhou M. A comparative study of azo dye decolorization by electro-Fenton in two common electrolytes. J Chem Technol Biotechnol, 2009, 84 (10): 1 544–1549.
[9] Gobbi L C A, Nascimento I L, Muniz E P, etal. Electrocoagulation with polarity switch for fast oil removal from oil in water emulsions [J]. Journal of Environmental Management, 2018, 13 (1): 119-125.
[10] Chen Guangguan, Hu Qi, et al. Electrocoagulation Treatment of Petroleum Cracking Catalyst Wastewater [J]. Journal of environmental engineering, 2015, 9 (10): 4850-4856.
[11] Swati S, Ahmet A, Halis S. Electrochemical treatment of sunflower oil refinery wastewater and optimization of the parameters using response surface methodology Chemosphere, 2020, 249: 126511.
[12] Khalifa O, Banat F, Srinivasakannan C, Radjenovic J, Hasan SW Performance tests and removal mechanisms of aerated electrocoagulation in the treatment of oily wastewater. J Water Pro Eng, 2020, 36: 101290.
[13] Flores N, Brillas E, Centellas F, etal. Treatment of olive oil mill wastewater by single electrocoagulation with different electrodes and sequential electrocoagulation/electrochemical Fenton-based processes [J]. Journal of Hazardous Materials, 2018, 347 (2): 58-66.
[14] Ting W. P., Huang Y. H., Lu M. C., Catalytic treatment of petrochemical wastewater by electro-assisted Fenton technologies [J]. React. Kinet. Catal. Lett, 2007, 92 (1): 41–48.
[15] Wang C. T., Hu J. L., etal, Removal of color from real dyeing wastewater by electro-Fenton technology using a three-dimensional graphite cathode [J] J Hazard, Mater. 2008, 152 (10): 601–606.
Cite This Article
  • APA Style

    Xiao Chen Xu, Ke Qiang Qiu. (2021). Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Engineering Science, 6(1), 12-16. https://doi.org/10.11648/j.es.20210601.12

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    ACS Style

    Xiao Chen Xu; Ke Qiang Qiu. Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Eng. Sci. 2021, 6(1), 12-16. doi: 10.11648/j.es.20210601.12

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    AMA Style

    Xiao Chen Xu, Ke Qiang Qiu. Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Eng Sci. 2021;6(1):12-16. doi: 10.11648/j.es.20210601.12

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  • @article{10.11648/j.es.20210601.12,
      author = {Xiao Chen Xu and Ke Qiang Qiu},
      title = {Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy},
      journal = {Engineering Science},
      volume = {6},
      number = {1},
      pages = {12-16},
      doi = {10.11648/j.es.20210601.12},
      url = {https://doi.org/10.11648/j.es.20210601.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.es.20210601.12},
      abstract = {Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy
    AU  - Xiao Chen Xu
    AU  - Ke Qiang Qiu
    Y1  - 2021/02/27
    PY  - 2021
    N1  - https://doi.org/10.11648/j.es.20210601.12
    DO  - 10.11648/j.es.20210601.12
    T2  - Engineering Science
    JF  - Engineering Science
    JO  - Engineering Science
    SP  - 12
    EP  - 16
    PB  - Science Publishing Group
    SN  - 2578-9279
    UR  - https://doi.org/10.11648/j.es.20210601.12
    AB  - Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.
    VL  - 6
    IS  - 1
    ER  - 

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Author Information
  • Material Science and Engineering College, Shenyang University of Technology, Shenyang, China

  • Material Science and Engineering College, Shenyang University of Technology, Shenyang, China

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